THE SCIENCE AND TECHNOLOGY CENTER IN UKRAINE
SUPERCONDUCTING NANOSTRUCTURAL MAGNESIUM%DIBORADE%BASED
MATERIAL FOR CRYOGENIC ELECTRICAL MACHINES
Description
At the Institute for Superhard Materials (ISM) of the
National Academy of Sciences of Ukraine (Kiev, Ukraine)
in cooperation with the Institut fur Physikalische
Hochtechnologie e.V. (IPHT, Jena, Germany), the super(cid:28)
conducting MgB2(cid:28)based nanostructural (15–37 nm aver(cid:28)
age grain size) materials with highest for nowadays super(cid:28)
conductive (Fig. 1) and mechanical characteristics have
been developed by high pressure (2 GPa)(cid:28)high tempera(cid:28)
ture (HP(cid:28)HT) synthesis. The materials have the following
characteristics: at 20 K critical current jc ≥ 1000–100
кÐ/Ñm2 up to 3 Т field and the field of the irreversibility
Hirr=8 Т, trapped magnetic field В=2 Т, hardness
ÐV=12.1 ± 0.08 GPa at P=4.9 N, fracture toughness
k1C=7.6± 2.0 МPа×m1/2, Young modulus Е=220 GPа and
near(cid:28)theoretical density. The MgB2 produced without
additions has a critical current density in zero magnetic
field of 780 kA/cm2 at 20 K and of 62 kA/cm2 at 35 K;
MgB2 with Zr added at 20 K in zero field has jc=1800
kA/cm2.
The MgB2 ingots can be HP(cid:28)HT synthesized in the shape
of cylinders up to 30 mm in diameter and 20 mm in height,
square plates of sizes up to 25×25×10 mm3 and rectangular
plates of sizes up to 25×21×10 mm3 (Fig. 2a). HP(cid:28)HT syn(cid:28)
thesized MgB2(cid:28)based materials are about tree times cheap(cid:28)
er than MT(cid:28)YBCO ceramics. Rather big rings or tubes can
be produced using precompaction by broaching with a sub(cid:28)
sequent sintering (Fig. 2b), jc = 8 kA/cm2 at 20 K. The
world(cid:28)first MgB2(cid:28)based electromotor has been construct(cid:28)
ed from high pressure(cid:28)high temperature synthesized MgB2
in cooperation with MAI and IPHT (Figs. 3, 4).
Fig. 1. Generalized de%
pendences of jc on magnet%
ic field, μμ0H, for HP%HT%
synthe%sized MgB2 without
and with additions of Ta,
Ti, Zr (2 and 10 wt %)
Fig. 2. View of MgB2 %based blocks HP%HT synthesized meas%
uring 17××17××5 mm3, 25.5××17××5 mm3 (a) and of a ring of size
D58××d53××h 22 mm synthesized at 1 Ar atm (b)
Fig. 3. MgB2%based rotor (40 mm in diameter and 75 mm long)
of SC motor manufactured in cooperation with the Moscow
State Aviation Institute, Russia (MAI) and IPHT (Jena,
Germany) and its characteristics at 20 K
Fig. 4. General view (a) and principal scheme (b) of the world%
first MgB2%based motor developed and constructed in the
MAI, from high pressure%high temperature synthesized MgB2
at the ISM
40
Innovative Aspect and Main Advantages
Interest for the electric machines that are working at the
liquid hydrogen temperature is caused by the modern
technological progress aimed at the substitution of fuel for
aircrafts, combustion engines of autotransport and water(cid:28)
transport (submarines) for hydrogen as well as due to the
development of the electrical power networks by which
the electrical power should be transmitted at a great dis(cid:28)
tances through the superconductive cables at the liquid
hydrogen temperature and using liquid hydrogen as cool(cid:28)
ing agent. Because of this the superconductive electromo(cid:28)
tors and pumps for liquid hydrogen, which are more effi(cid:28)
cient than the traditional ones due to the essentially lower
weight, much higher speed of operation in the reversion
regime and higher specific output power on the rotor sur(cid:28)
face, will be of a high demand when changing to technolo(cid:28)
gies utilizing liquid hydrogen. MgB2(cid:28)based materials are
rather cheap and easily produced. With increased dimen(cid:28)
sions of the high(cid:28)pressure chamber, it would be possible to
produce blocks of higher dimentions.
Areas of Application
Nanostructural MgB2(cid:28)based materials nowadays are most
promising for cryogenic machines and devices (magnetic
bearings, MAGLEV transport, electromotors, pumps for liq(cid:28)
uid gases, fly(cid:28)wheels energy storage systems, fault current
limiters, etc.) working at hydrogen temperatures (20 K).
Stage of Development
The developed nanostructural MgB2(cid:28)based material (UA
patent 68888 Ð) has at present the highest level of super(cid:28)
conductive characteristics known for MgB2(cid:28)based materi(cid:28)
als from literature. The comparative tests of MgB2(cid:28)based
and MT(cid:28)YBCO(cid:28)based motors at the same temperature
conditions have shown that MgB2(cid:28)based motor competi(cid:28)
tive in such applications.
Contact Details
Contact person: Prikhna Tatiana
Institute for Superhard Materials of the NAS of Ukraine
Address: 2, Avtozavodskaya Str. , 04074 Kiev, Ukraine
Tel/Fax: (380(cid:28)44) 430(cid:28)11(cid:28)26
Mob.: 8(097) 467(cid:28)18(cid:28)27
E(cid:28)mail: prikhna@mail.ru, prikhna@iptelecom.net.ua
SCIENCE AND INNOVATION. Special Issue, 2007
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