THE SCIENCE AND TECHNOLOGY CENTER IN UKRAINE
Fig. 1. Scheme of deposition installation and SHG signal from
dye%in%polymer film
Fig. 2. Plasmon band change during deposition and TEM image
of Au%filled nanocomposite polymer films
POLYMER, DYE AND ORGANIC%INORGANIC NANOCOMPOSITE FILM
VACUUM TECHNOLOGIES
Description
25 years experience in all chain necessary for develop(cid:28)
ments: compound modeling, design and synthesis, thermal,
electron gun, laser, plasma, CVD and combinations of that
technologies in one run for production of nano(cid:28)composite
films, film characterization in situ by optical spectroscopy,
than by AFM, TEM, X(cid:28)Ray, modeling of nano(cid:28)composite
properties, sensor, electric etc. properties measurements.
1. Deposition technologies for Teflon (PTFE), polypara(cid:28)
phenylene sulfide (PPS) and Parylene polymer films.
Experimental installations exist. Polymer films can be used
for low(cid:28)k dielectric, barrier and protective layers in OLED,
OFET, FPD, medicine.
2. Synthesis and deposition technology of new asymmetric
evaporable dyes. Co(cid:28)polymerisable in vacuum dyes. Linear
and plane evaporators.
3. Metal(oxide)(cid:28)dye(cid:28)polymer nanocomposite films.
Materials and deposition technologies.
4. Multi(cid:28)layered systems.
5. Waveguide optical sensor, as well electrical.
Innovative Aspect and Main Advantages
Most robust insoluble polymers for aggressive environ(cid:28)
ment. Dye synthesis taking into account deposition tech(cid:28)
nology as well. No liquid during deposition of multi(cid:28)lay(cid:28)
ered systems. Combination of different kinds of materials
in one nanocomposite film with new properties. Easy pro(cid:28)
duction of gradient films. Standard base industrial vacuum
equipment.
Areas of Application
PTFE deposition technology are or great importance as
the best low(cid:28)k dielectric for the next generation of
microchips. PTFE films filled with metal and dye nano(cid:28)
clusters can find applications in chemical catalysis,
biochips, photonics devices. PTFE, PPX and PPS can be
used in waveguide as materials with low and high refrac(cid:28)
tive indices. Filled with asymmetric nonlinear or sensor
dyes polymer waveguides are able to execute active func(cid:28)
tions in integrated(cid:28)optic devices. We offer PPX monomer
generation installations at small sum, than. The evapora(cid:28)
tion of dye and polymer need special evaporation devices,
which can not be copied from ones existing for inorganic
materials. The control devices also have to be special. We
have some previous developments for these problems. US
Consortium for FPD spent $300,000.00 to resolve the
problems, but they still far from the optimal.Organic func(cid:28)
tional materials are developed for organic electronics and
photonics. The market of OLED, FPD, OFET and photo(cid:28)
voltaic devices to be billions dollars in close time. We con(cid:28)
sider our developments as ready for presentation for far(cid:28)
ther development of technologies and installations on
industrial level.
54
Stage of Development
Polymer, dye and nanocomposite film deposition technolo(cid:28)
gies and installations on R&D level. New dyes develop(cid:28)
ment and synthesis on scientific level. New materials and
technologies for OLED and nano(cid:28)photonics on scientific
level.
Contact Details
Contact person: Konstantin Grytsenko
Institute of Semiconductor Physics
Address: 45 pr. Nauki, Kyiv 03028, Ukraine
Tel: +380 44 525 97 06 Fax: +380 44 525 55 30
E(cid:28)mail: D_gryts@isp.kiev.ua D_gryts@hotmail.com
Web(cid:28)site: www.geocities.com/grytsenkok/index.html
Fig. 3. New evaporable asymmetric dyes
SCIENCE AND INNOVATION. Special Issue, 2007
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