NEW ANTI – STOKES LUMINOPHORS AND LASER MEDIUMS ON THE
- VI4 TYPED WIDE-BAND CHALCOGENIDE
BASE OF II-III 2
SEMICONDUCTORS DOPED BY RARE-EARTH ELEMENTS
length
is
activation
Therefore
systems of
lines where data carrier
Description
Traditional investigations, synthesis and use of anti –
Stokes luminophors (ASL) have an objective to
visualize IR-radiation, i.e. IR-signal conversion into
visible band (0.38÷ 0.76mkm). Recently there have
fiber optic
been created
communication
the
radiation with wavelength about 1.55 mkm. There
have been developed lasers on the base of erbium
glasses with wavelength of generation 1.54÷1.65
mkm.
of wide-band
semiconductive compounds EuGa2S4 and YbGa2S4 by
4f-elements, study of impurity state and behavior is
one of the central issues of physics and material
science of semiconductors as a whole.
Nowadays complex rare – earth compounds of
VI- S,Se) –
MIM2
typed take a special place among wide - band
semiconductors.
VI - typed crystals have been crystallized in
IIX4
MIM2
are high –resistance
rhombic
singony,
(105÷10IIOhm/cm),
(~4.4eV)
semiconductors and show particularly pronounced
luminescent and photoconductive properties.
VI (MI -Eu, Yl,Sm; MII-Ga,In; X4
wide-band
IIX4
they
In according with above- mentioned it is of interest
spectroscopic investigation of 4f-elements in Eu (Yb)
Ga2S4 crystals.
There has been developed technology of II-III2 - IV2
(II-Eu, Yb,Sm,Ca, Sr,Ba; III-Ga,Al;VI-S,Se,O) -
typed semiconductors activated by rare-earth ions.
necessity
properties. This
Innovative Aspects and Main Advantages
Production of effective devices for visualization and
illumination, being able to compete with traditional
systems requires to manufacture luminophors with
specific
promotes
development of new materials and optimization of
existing luminophors. İn this aspect perspective ones
are ternary alkali-earth chalcogenide semiconductors
of II-III2 - IV2 (II-Eu, Yb,Sm,Ca, Sr,Ba; III-Ga,Al;VI-
S,Se,O) – typed activated by rare-earth ions. One of
the qualities of
ternary compounds comparing
favourably with binary one as regards applied use is
the resistance to hydrolysis and good implantation of
rare-earth ions into crystal lattice. High linearity of
cathode luminescence at high densities of current
makes them suitable for use as a luminophor in TV
and
Selection of
corresponding sensitizers and activators one can
change efficiency of conversion of various kinds of
energy into light one and luminescence colors of these
compounds.
ionization displays.
field
Areas of Application
Systems of fiber optic communication lines, lasers with
wavelength of generation 1.54-1/65mkm, night vision
equipments.
Stage of Development
Development phase - laboratory tested.
Fig.1………
Fig.2………….
Contact Details
Institute of Physics
Contact person: Tagiev Oktay Bahadur
Address: 33, H. Javid Avenue
AZ1143, Baku, Azerbaijan
Tel: (994 12) 439 6795
Fax: (994 12) 447 0456
E-mail: oktay58@mail.ru
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