SCIENTIFIC INNOVATIVE PROJECTS FROM MINISTRY OF EDUCATION AND SCIENCE
AND NATIONAL ACADEMY OF SCIENCES OF UKRAINE
Fig. 1. Formation of nanocomposite in liquid metallic matrix
powder allows to form a porous metallic alloys more effec(cid:28)
tively in comparison with other methods. Using of
obtained results allowed us to reduce the density of Al(cid:28)
based alloys with improving of their properties.
Areas of Application:
The obtained results are interested for material science and
technology especially at producing of materials with
improved mechanical, corrosive resistance and other prop(cid:28)
erties. They can be used in such branches of industry:
– aircraft and machine building;
– chemical engineering;
– electrical engineering.
FORMATION OF NANOCOMPOSITE SYSTEMS BY MEANS
OF SOLID%LIQUID REACTIONS
Description:
It is known that presence of nanoclusters in composite sys(cid:28)
tems improves the most number of physical (cid:28) chemical
properties. Unfortunately the obtaining of such systems is
associated with different kind of problems (e.g. technolog(cid:28)
ical, technical and others). It is also important to have a
fundamental information about changes of structure in
nanocomposite synthesis process and to understand their
influence on the formation of main working properties for
different materials produced on the base of these compos(cid:28)
ites. We propose to use the mixture of dispersed fine pow(cid:28)
der and molten metal in order to obtain the nanocompos(cid:28)
ite systems. The tendency to solid(cid:28)liquid chemical interac(cid:28)
tion depends on nature of elements contained in both liq(cid:28)
uid and solid phases.The formation of multicomponent
system with different size of constituents including the
nanoscale ones can be governed by changing the tempera(cid:28)
ture and duration of solid(cid:28)liquid chemical reaction. The
pre(cid:28)treatment of powder in inert gas atmosphere is allowed
in addition to solid structural units also produce the gas
filled pores. Consequently, the density of composite will be
reduced without the main properties losses.Eutectic Al(cid:28)Si
and Al(cid:28)Cu alloys mixed with dispersed fine Ni powder of
1μm size have been studied. Both the common and the
small angles X(cid:28)ray diffraction studies of system structure
dependently on temperature and duration of chemical
reaction enable the definition of the main principles of
nanocomposite structure formation and the optimization
of solid(cid:28)liquid reaction parameters.
Stage of Development:
Development phase (cid:28)laboratory tested
Innovative Aspect and Main Advantages:
Existing methods for obtaining of composite systems by
means of liquid(cid:28)solid chemical reactions do not account
the dependence of formed phases size on reaction duration
and temperature whereas the main attention is attracted to
both element and phase content. We consider the possibil(cid:28)
ity to reduce the dispersed powder size down to nanoscale
one in order to form the various phases via chemical reac(cid:28)
tion way and consequently to improve the properties of
composite. Accumulating the gas in pores of dispersed
Contact Details:
Ivan Franko National University, Physics of Metal
Department,
Contact person: Stepan Mudryy
Address: Kyrylo and Mephodiy str., 8, Ua(cid:28)79005 Lviv,
Ukraine
Telephone: +380(cid:28)322(cid:28)964594
Email: mudry@physics.wups.lviv.ua
Website:
http://www.physics.wups.lviv.ua:8102/depts/KFM/index
_ua.html
78
SCIENCE AND INNOVATION. Special Issue, 2007
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